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Supplement Schedule

When you take a supplement matters almost as much as what you take. This schedule is based on absorption science, circadian biology, and mineral competition research. Each recommendation links to the PubMed study behind it.

You don't need all of these — this is a reference for optimal timing of whatever you're taking. Use the filter to find your supplements.

Key Principles

Mineral competition

Zinc, iron, calcium, magnesium, copper, and manganese share transporters (DMT1). Taking them together reduces absorption of each. Separate competing minerals by 2-4 hours.

PMID: 1600930

Fat-soluble vitamins need fat

Vitamins D, K2, CoQ10, astaxanthin, and curcumin require dietary fat for absorption via micelle formation. Always take with a fat-containing meal.

PMID: 20200983

Splitting doses improves absorption

Water-soluble vitamins like C have saturable intestinal transporters. Splitting doses maintains higher plasma levels than one large dose.

PMID: 8623000

Circadian timing matters

The gut has its own circadian clock. Gastric acid, enzyme expression, and transporter activity all follow daily rhythms. Energizing supplements morning, calming ones evening.

PMID: 24012542

Taking many at once is fine — with caveats

Most supplements can be taken together without issue. The exceptions are competing minerals and certain specific interactions noted in each entry. Grouping by time block is the safest approach.

Iron is the most timing-sensitive

Iron absorption is uniquely complex — alternate-day dosing may outperform daily due to hepcidin kinetics. Always separate from calcium, zinc, coffee, tea, and turmeric.

PMID: 28389369
7:00 AM

Morning — Empty Stomach

30 minutes before breakfast. Best for amino acids, certain herbs, and compounds that compete with food for absorption.

Probiotics

Gastric acid is lowest upon waking. Taking before food gives bacteria transit through a less acidic stomach.

Take with Small amount of water
Avoid with Hot beverages (kills bacteria), antibiotics
Frequency Daily
PMID: 21901293

NAC

Only 6-10% bioavailability — food (especially protein) further reduces absorption due to competition with dietary cysteine.

Take with Vitamin C (synergistic for glutathione recycling)
Avoid with Protein meals, activated charcoal
Frequency Daily
PMID: 1967767

L-Glutamine

Competes with other amino acids for absorption. Fasted state allows direct uptake by intestinal lining.

Take with Water only
Avoid with Large protein meals
Frequency Daily (5-10g)
PMID: 11533317

Sulforaphane

Activates Nrf2 antioxidant pathway. Nrf2 target gene expression has circadian gating — peaks during the morning active phase.

Take with Mustard seed powder (myrosinase source)
Avoid with No major conflicts
Frequency Daily
PMID: 24012542

Alpha-Lipoic Acid

Food reduces bioavailability by ~30%. Both water and fat soluble, so no fat needed. Mildly energizing.

Take with Acetyl-L-Carnitine (the "Ames combo" for mitochondria), Biotin
Avoid with Food, thyroid medication (4hr gap)
Frequency Daily
PMID: 12388164

Berberine

Activates AMPK and blunts postprandial glucose spikes. Best 15-30 min before a carb-containing meal.

Take with Milk thistle or piperine (may improve bioavailability)
Avoid with Statins, blood thinners, CYP3A4 medications
Frequency Daily before meals; some cycle 8 weeks on/2 off
PMID: 18442638
7:30 AM

Morning — With Breakfast

Take with a fat-containing meal. Fat-soluble vitamins need micelles for absorption. This is also the time for stimulating adaptogens.

Vitamin D

32% higher absorption with a fat-containing meal. May suppress melatonin — avoid evening dosing.

Take with Vitamin K2, Magnesium (cofactor for D metabolism), fat source
Avoid with Mega-dose calcium, evening dosing
Frequency Daily
PMID: 20200983

Vitamin K2

Fat-soluble. Directs calcium to bones and away from arteries. MK-7 has a 72hr half-life; MK-4 is much shorter.

Take with Vitamin D, fat source, Vitamin A
Avoid with Warfarin/blood thinners
Frequency Daily
PMID: 28698808

CoQ10

Absorption increases 3x with fat. Energizing — supports mitochondrial ATP production.

Take with Fat source, PQQ (synergistic for mitochondria), Shilajit
Avoid with Bedtime (may disrupt sleep)
Frequency Daily
PMID: 17482773

PQQ

Promotes mitochondrial biogenesis via PGC-1alpha. Energizing — morning aligns with daytime energy needs.

Take with CoQ10 (PQQ makes new mitochondria, CoQ10 fuels them), fat source
Avoid with Bedtime
Frequency Daily
PMID: 23092675

B-Vitamins

Energizing — participate in energy metabolism. B6 and B12 may disrupt sleep if taken in evening.

Take with Food (reduces nausea from B3)
Avoid with Bedtime
Frequency Daily
PMID: 27989568

Astaxanthin

Highly lipophilic — 2.4-3x better absorption with a fat-containing meal. Accumulates over weeks.

Take with Omega-3 fish oil, other fat-soluble vitamins
Avoid with Fat-blocking agents
Frequency Daily
PMID: 22428137

Rhodiola

Stimulating — increases dopamine and norepinephrine by inhibiting COMT and MAO. Improves fatigue and stress.

Take with Other morning adaptogens (ginseng, cordyceps)
Avoid with Evening (insomnia), SSRIs
Frequency Daily; some cycle 5 on/2 off
PMID: 22228617

Cordyceps

Enhances oxygen utilization and ATP production. Performance-enhancing and energizing.

Take with CoQ10, PQQ (mitochondrial support)
Avoid with Bedtime, immunosuppressants
Frequency Daily
PMID: 20804368

Creatine

Timing isn't critical — accumulates over weeks. Carbs and protein improve uptake via insulin.

Take with Carbohydrates/protein (60% better loading)
Avoid with No major conflicts
Frequency Daily (3-5g)
PMID: 7572228

NMN / NAD+

NAD+ biosynthesis enzyme NAMPT is clock-controlled, peaking during the active phase. Morning maximizes conversion.

Take with Resveratrol (SIRT1 activator needs NAD+ substrate), TMG
Avoid with Bedtime (mildly energizing)
Frequency Daily
PMID: 19229278

Iodine

Supports thyroid hormone synthesis. TSH peaks at night, T3/T4 peak in morning — provides substrate when production ramps up.

Take with Selenium (cofactor for T4→T3 conversion)
Avoid with High doses with Hashimoto's (without supervision)
Frequency Daily
PMID: 20172476

Selenium

Essential for glutathione peroxidase and thyroid deiodinases. Pairs with iodine for thyroid support.

Take with Iodine, Vitamin E
Avoid with High-dose Vitamin C (with inorganic selenium only)
Frequency Daily (max 400mcg)
PMID: 11115795

Boron

Supports calcium/magnesium/vitamin D metabolism. May reduce SHBG, increasing free testosterone — morning aligns with peak T production.

Take with Calcium, magnesium, vitamin D
Avoid with No major conflicts at 3-6mg
Frequency Daily
PMID: 21129941

Shilajit

Contains fulvic acid that enhances CoQ10 levels. Mildly energizing. Fulvic acid may improve absorption of other supplements.

Take with CoQ10 (synergistic)
Avoid with Evening (stimulating for some)
Frequency Daily
PMID: 22482077

Bacopa

Fat-soluble bacosides need dietary fat. Cognitive benefits take 8-12 weeks. Morning aligns with cognitive demand.

Take with Fat source, Lion's Mane (complementary nootropics)
Avoid with Anticholinergic meds, thyroid meds
Frequency Daily for 8-12+ weeks
PMID: 24252493

Vitamin C

Absorption saturates above 200mg per dose. Split dosing (morning + midday) maintains higher plasma levels than one large dose.

Take with Iron (if supplementing — 2-3x absorption boost), Collagen
Avoid with High-dose cyanocobalamin B12 (use methylcobalamin instead)
Frequency Daily, split doses
PMID: 8623000
12:30 PM

Midday — With Lunch

Best for minerals that compete with your morning stack. Separating minerals by 4+ hours prevents absorption competition.

Iron

Must separate from calcium, zinc, and magnesium by 2-4 hours. Alternate-day dosing may be better — hepcidin rises after ingestion and suppresses absorption for ~24 hours.

Take with Vitamin C (50-100mg), light food if GI-sensitive
Avoid with Calcium, zinc, magnesium, coffee, tea, turmeric, dairy, antacids
Frequency Every other day may be superior to daily
PMID: 28389369

Zinc

Separate from iron and calcium. Zinc picolinate and bisglycinate have superior absorption. Nausea common on empty stomach.

Take with Protein-containing meal, Vitamin B6
Avoid with Iron, calcium, phytates, high-dose copper
Frequency Daily; >30mg/day needs copper co-supplementation
PMID: 3630857

Chromium

Enhances insulin signaling — potentiates insulin receptor activity. Best with a carb-containing meal.

Take with Carbohydrate-containing meal, Vitamin C
Avoid with Antacids, iron (at very high doses)
Frequency Daily with meals
PMID: 10422769

Quercetin

Bioavailability improves with fat and is enhanced by vitamin C. Anti-inflammatory and antihistamine. Timing is flexible.

Take with Fat source, Vitamin C, Bromelain (improves absorption)
Avoid with Cyclosporine, certain antibiotics (fluoroquinolones)
Frequency Daily
PMID: 15670984

Resveratrol

Low bioavailability (~1%). Piperine can improve absorption. Activates SIRT1 (which needs NAD+ substrate).

Take with NMN/NAD+ precursors, Piperine, Quercetin, fat source
Avoid with High-dose aspirin, CYP3A4 medications
Frequency Daily
PMID: 20026311

Vitamin C (2nd dose)

Split dosing maintains higher plasma levels due to saturable intestinal absorption (SVCT1 transporters).

Take with Iron (if supplementing at this time)
Avoid with See morning notes
Frequency Daily
PMID: 8623000
6:30 PM

Evening — With Dinner

Take with a fat-containing meal. Best for calming adaptogens, anti-inflammatories, and compounds that support overnight repair.

Omega-3 (Fish Oil)

Fat-soluble — significantly higher absorption with a high-fat meal. Evening aligns with anti-inflammatory overnight repair. May improve sleep quality.

Take with Fat source, Vitamin E (prevents oxidation), Curcumin, Astaxanthin
Avoid with Blood thinners at very high doses (>3g/day)
Frequency Daily
PMID: 31067776

Turmeric / Curcumin

Lipophilic — needs fat. Piperine increases bioavailability by 2000%. Anti-inflammatory effects work during overnight repair phase.

Take with Fat source, Piperine/black pepper, Boswellia, Omega-3
Avoid with Iron supplements (chelates iron), blood thinners
Frequency Daily
PMID: 9619120

Ashwagandha

Reduces cortisol by ~30%. GABA-mimetic and calming. Evening aligns with the need to lower cortisol for healthy sleep onset.

Take with Fat-containing food, Magnesium
Avoid with Thyroid medications (may increase thyroid hormones), immunosuppressants
Frequency Daily; some cycle 6-8 weeks on/2 off
PMID: 23439798

Magnesium

Calming — blocks NMDA receptors, enhances GABA. Supports sleep onset and muscle recovery. Glycinate form best for sleep.

Take with Vitamin D, Vitamin B6 (enhances intracellular transport)
Avoid with Iron, antibiotics (separate by 2hr)
Frequency Daily (most adults are deficient)
PMID: 23853635

Taurine

Inhibitory — modulates GABA-A and glycine receptors. Calming. Cardioprotective during overnight cardiovascular function.

Take with Magnesium, Glycine
Avoid with Morning if optimizing alertness
Frequency Daily (1-3g)
PMID: 22855308

Collagen

Collagen synthesis peaks during sleep when growth hormone is highest. Evening provides amino acid building blocks for overnight repair.

Take with Vitamin C (essential cofactor for collagen hydroxylation)
Avoid with No major conflicts
Frequency Daily (10-15g)
PMID: 26840887

Reishi

Calming and mildly sedating. Triterpenes modulate GABA pathways. Traditional "spirit-calming" evening mushroom.

Take with Ashwagandha, hot water (improves triterpene solubility)
Avoid with Immunosuppressants, blood thinners
Frequency Daily (dual-extract preferred)
PMID: 22207209

Milk Thistle

Supports liver detox. Many CYP450 enzymes peak in evening/night. Evening provides substrate during peak hepatic activity.

Take with Fat source (lipophilic), phosphatidylcholine-bound form preferred
Avoid with CYP2C9/CYP3A4 medications (modest inhibition)
Frequency Daily
PMID: 26232459

Holy Basil

Adaptogen with anxiolytic and cortisol-lowering properties. Reduced stress and anxiety by 39% in studies.

Take with Ashwagandha, Magnesium
Avoid with Blood thinners, diabetic medications (additive)
Frequency Daily
PMID: 22614091
10:00 PM

Bedtime

30-60 minutes before sleep. Calming amino acids, sleep-support compounds, and overnight repair substrates.

Glycine

Lowers core body temperature via NMDA receptors in the SCN, triggering sleep onset. Improved sleep quality without morning grogginess.

Take with Magnesium glycinate, L-Theanine
Avoid with No major conflicts
Frequency Nightly (3g)
PMID: 17693028

L-Theanine

Increases alpha brain waves within 30-40 minutes. Boosts GABA, serotonin, and dopamine. "Alert relaxation" — calming without sedation.

Take with Magnesium, Glycine. During the day: pairs with caffeine to smooth jitteriness.
Avoid with No major conflicts. Very safe.
Frequency Nightly or as needed (200mg)
PMID: 18296328

Melatonin

Chronobiotic — shifts circadian phase. Lower doses (0.3-0.5mg) are often more effective than high doses (5-10mg) which cause morning grogginess.

Take with Magnesium (cofactor for AANAT, rate-limiting melatonin enzyme), complete darkness
Avoid with Bright light/screens, alcohol, long-term high doses
Frequency Short-term or intermittent; consider cycling 5 on/2 off
PMID: 15956094

5-HTP

Immediate precursor to serotonin, which converts to melatonin at night. Supports the natural serotonin→melatonin pathway.

Take with Vitamin B6 (P5P form — cofactor for the converting enzyme), Magnesium
Avoid with SSRIs, SNRIs, MAOIs, tramadol, triptans (serotonin syndrome risk)
Frequency Intermittent or short-term preferred
PMID: 18498676

Valerian

Valerenic acid inhibits GABA breakdown, increasing GABA levels. Modest sleep quality improvement over 4-8 weeks.

Take with Other sleep herbs (passionflower, lemon balm)
Avoid with Sedatives, alcohol (additive)
Frequency Daily for 4-8 weeks; benefits build over time
PMID: 16619359

Passionflower

GABA-A receptor modulator via chrysin and other flavonoids. Comparable to oxazepam for anxiety in one study.

Take with Valerian, Lemon Balm
Avoid with Sedatives (additive)
Frequency Daily
PMID: 11679026

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